Title : Studies on heterocyclic immobilized with cyanoguanidine decorated magnetic GO as innovative, powerful, and recyclable nanocatalysts for the synthesis of spire [indole-3,2- thiazolidine]-2,4 (1H)-diones
Abstract:
Heteropolyacids have created increasing research interest due to their outstanding properties,This idea make us to synthesize a novel nanocatalyst was via HPA immobilization of magnetic graphene oxide - cyanoguanidine composite. The catalytic performance created was employed in a multi-component reaction, A mixture of isatin ,thioglycolic acid, various primary amines and H3PW12O40@Co3O4/GO/La2O3/CG as catalyst was dissolved in water and in an ultrasonic bath for appropriate times, the completion of the reaction was checked by TLC and then the catalyst was magnetically separated. Finally, the crude precipitate was filtered and then recrystallized from EtOH to obtain a pure solid product. The products were investigated by 1H NMR, 13C NMR, IR.